2-D MXene flakes as potential replacement for both TCO and Pt layers for dye-sensitized solar cell

Muhammad Shakeel, Ahmad and Pandey, Adarsh Kumar * and Nasrudin Abd Rahim and Aslfattahi, Navid and Mishra, Yogendra Kumar and Rashid, Bushra and Saidur, Rahman * (2021) 2-D MXene flakes as potential replacement for both TCO and Pt layers for dye-sensitized solar cell. Ceramics International, 47 (19). pp. 27942-27947. ISSN 0272-8842

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Abstract

The counter electrode (CE) containing catalyst layer and transparent conducting oxide (TCO) layer is by far the most expensive components in Dye sensitized solar cells (DSSC) due to use of rare earth element such as Pt. The potential replacement of both the TCO layer and Pt-based catalyst would essentially pave the way to mass commercialization of the technology of DSSC. In this investigation, an attempt has been made to replace both TCO and Pt with a single layer of delaminated 2-D MXene (Ti3C2) being produced by the leaching method which acted as both conducting layer and catalyst. Furthermore, the thickness of Ti3C2 has been optimized for maximum conversion efficiency. The TCO-Pt-free MXene based CEat optimum thickness exhibited a remarkable 8.68% conversion efficiency outperforming the standard TCO-Pt-based CE by 4.03%. The high efficiency is due to high conductivity, high available catalytic cites due to delaminated structure, and good catalytic activity of Ti3C2 towards iodide/triiodide electrolyte.

Item Type: Article
Uncontrolled Keywords: catalytic activity; counter electrode; DSSC; MXene; TCO-Pt-free
Subjects: Q Science > QD Chemistry
T Technology > TP Chemical technology
Divisions: Sunway University > Faculty of Engineering and Technology [formerly School of Engineering and Technology until 14 November 2025; School of Science and Technology until 2020] > Research Centre for Nano-Materials and Energy Technology
Depositing User: Ms Yong Yee Chan
Related URLs:
Date Deposited: 11 Jul 2026 03:01
Last Modified: 11 Jul 2026 03:01
URI: http://repository.sunway.edu.my/id/eprint/3473

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